On-surface UHV chemistry

High-resolution SPM imaging allows us to identify the chemical structure of molecular reactants and products on surfaces under UHV. We try to explore new routes to driven chemical reactions not only on metal but also on insulating surfaces using different external stimuli (heat, light, tunneling electrons, etc.).



 

O. Stetsovych, M. Švec, J. Vacek, J. Vacek Chocholoušová, A. Jančařík, J. Rybáček, K. Kosmider, I. G. Stará, P. Jelínek, I. Starý 
From helical to planar chirality by on-surface chemistry 
Nat. Chem. 9 (2017) 213 - 218.

 

J. Hellerstedt, A. Cahlík, M. Švec, B. de la Torre, M. Moro-Lagares, T. Chutora, B. Papoušková, G. Zoppellaro, P. Mutombo, M. Ruben, R. Zbořil, P. Jelinek 
On-surface structural and electronic properties of spontaneously formed Tb2Pc3 single molecule magnets 
Nanoscale 10 (2018) 15553 - 15563.

 

J. Hellerstedt, A. Cahlík, O. Stetsovych, M. Švec, T. K. Shimizu, P. Mutombo, J. Klívar, I.G. Stará, P. Jelínek, I. Starý
Aromatic Azide Transformation on the Ag(111) Surface Studied by Scanning Probe Microscopy 
Angew. Chem. Int. Ed. 58 (2019) 2266 - 2271.

 

A. Sánchez-Grande, B. de la Torre, J. Santos, B. Cirera, K. Lauwaet, T. Chutora, S. Edalatmanesh, P. Mutombo, J. Rosen, R. Zbořil, R. Miranda, J. Bjork, P. Jelínek, N. Martín, D. Ecija
On‐surface synthesis of ethynylene bridged anthracene polymers 
Angew. Chem. Int. Ed. 58 (2019) 6559 - 6563.

 

J. Su, M. Telychko, P. Hu, G. Macam, P. Mutombo, H. Zhang, Y. Bao, F. Cheng, Z.-Q. Huang, Zh. Qiu, Sh. J. R. Tan, H. Lin, P. Jelínek, F.-Ch. Chuang, J. Wu, J. Lu
Atomically precise bottom-up synthesis of π-extended [5]triangulene 
Science Advances 5 (2019) eaav7717-1 - eaav7717-6.

 

B. Cirera, B. de la Torre, D. Moreno, M. Ondráček, R. Zbořil, R. Miranda, P. Jelínek, D. Écija
On-Surface Synthesis of Gold Porphyrin Derivatives via a Cascade of Chemical Interactions: Planarization, Self-Metalation, and Intermolecular Coupling 
Chem. Mater. 31 (2019) 3248 - 3256.

 

F. Queck, O. Krejčí, P. Scheuerer, F. Bolland, M. Otyepka, P. Jelinek, J. Repp
Bonding Motifs in Metal-Organic Compounds on Surfaces 
J. Am. Chem. Soc. 140 (2018) 12884 - 12889.